(06-16-2010 05:38 PM)ForcedInduction Wrote: (06-16-2010 02:43 PM)RustyLugNut Wrote: The sweeping conclusion that HHO doesn't work because the tested units don't work, is not a valid scientific conclusion.
Wrong. They don't work because they would have to violate several fundamental laws of science to do so. Its not a matter of design, trial and error or human ingenuity, its nature.
Several years ago Windsor University ran an HHO test using dry bottled gasses to simulate an electrolyser output without the variable of ingested water vapor. The research paper conclusion statement is of the proper form. "As tested, the HHO gas mix" produced a "net loss of energy" as measured on the dynomometer. The "as tested" part of the statement is true, since their tests were not all encompassing. They didn't tune or modify the test engine to try to take advantage of the augmenting hydrogen. The PopMech article should have followed suit in its conclusions. But then again, like the TV show Mythbusters, they are in the entertainment business and do not need to submit to peer review.
When viewed from a macroscopic perspective and viewing the fuel as two separate combustible gases - your conclusion becomes obvious. The gasoline or diesel, which ever the case may be, must be assisted by a combustible mix of hydrogen which must burn independent of the hydrocarbon fuel with enough pressure to result in a net energy gain above the energy expended to produce the hydrogen through electrolysis. The 4% LFL (lower flammability limit ) by volume of hydrogen would dictate the need to produce liters per second of hydrogen for all but the smallest engines. Electrolysis generators cannot provide this volume of hydrogen flow without an inordinate amount of engine power resulting in a net loss of energy.
However, if we view the interaction of hydrogen radicals on the hydrocarbon fuel, we see that a decrease in BSFC ( Brake Specific Fuel Consumption ) is possible without breaking any fundamental laws of chemistry and physics.
If you take our test subject engines ( both 1984 model 4 cylinder, 2.2 liter, gasoline and diesel engines, respectively), you can see that an idle speed of 600 rpm ( 10 cycles per second) results in 5 intake events per second leading to an ingestion of 2.75 liters of air ( for the unthrottled diesel engine, much less for the gasoline engine ) per cylinder per second. Add to this a flow resulting from 1 ampere of current running through an electrolysis cell. This results in one coulomb equivalent of hydrogen ( 6.24x10E18 ) being ingested into the same 2.75 liters of air. When compressed to 8:1 (Dodge gas engine) or 22:1 ( Mercedes diesel ) the resulting increase in pressure and temperature produce highly reactive H+ radicals that railroad the production of side radicals and strip even more hydrogen atoms from the hydrocarbon chain within a few picoseconds of the start of ignition. A domino effect of H+ radicals stripping more hydrogen from their carbon bonds resulting in even more H+ radicals to do the same, means that if the variables of initial H+ concentration, turbulence, temperature and pressure are correct, a hydrogen mixture exceeding the required LFL for combustion is achieved resulting in the fuel mix releasing its heat energy in a narrower time period. If this heat release is narrow enough and timed correctly, most of the pressure gain will fall in the area 0 - 180 degrees after TDC resulting in an increase in the BMEP ( Brake Mean Effective Pressure ). A small increase in BMEP results in a several horsepower gain for the expenditure of a few hundred watts of electrical power.
' Wrote:Electrolysis has been around for 203 years, the internal combustion automobile 116 years. In all that time of milti-million$ R&D budgets, thousands of genius minds (Ford, Edison, Westinghouse, Tesla just to name a few), millions of independent designers, millions of independent testers and millions of failures, don't you think it stands to reason that if it were possible that at least one of them would have been made into a working, reproducible, prototype by now?
Need. There was no need for it. Economy and emissions were not a concern until the last few decades. An obscure German device from 1911 used an alkaline electrolyser to produce "make up" hydrogen for Zeppelin airships and give them more flight time. The drawings also show manifolding that directs the gas output into the intake of the aero engines. I can find no evidence that it was ever implemented and used, but it shows someone was thinking along such lines a long time ago.
Dozens of patented devices have been devised to increase efficiency and reduce emissions over the years. They never reached prototype or production status because there was no perceived need for lowered fuel use and emissions. Until they were needed. Then they were revisited and revised.
The principle of catalytic conversion has been known for a hundred years plus, but it took legislation in the 70's to see its production and implementation as the current catalytic converter on cars.
Mitsubishi's stratified charge engines of the 70's and Toyota's direct injection engines of the 80's now result in direct injected lean burn engines that EVERY manufacturer is looking to bring into their engine line ups.
That mythical 200 mpg carburetor from the 30's? You can see a direct and modern attempt at it's execution in the work of a small company in Oregon. Will it see production use? Maybe, maybe not. But it does reduce fuel use by 30% and emissions are also greatly reduced. And it has been tested by EPA certified labs.
Private corporations as well as colleges and Universities are pulling in loans, grants and government handouts to deepen our understanding of combustion and the questions of increased efficiency and reduced emissions. A local university just a few miles from our office has benefited in the way of an EPA quality testing lab facility installed on campus for use in research.
The need is here, now.
' Wrote:Quote:you will realize you don't need much HHO to have an effect on combustion
Just about a liter per second. Much more if you want to run the engine directly on hydrogen.
I answered this in the above discussion. You continue looking at the fuels in parallel. However, the fuel interaction is the key. Is it enough to obtain 200-300% greater fuel economy in current automobiles? Not a chance! But, a relatively small inclusion of hydrogen in a hydrocarbon fuel effects the oxidation paths measurably - assuming you add enough pressure, turbulence and temperature.
' Wrote:Quote:At least we haven't seen it, but 10 to 15% seems like very realistic reduction of BSFC.
If thats all you can hope for then its far cheaper, less maintenance intensive and proven that using an Atkinson cycle camshaft will return that much efficiency.
The original question seemed to be: " does HHO work"? I have answered that in principles of science. Now you are asking, "is HHO economically viable"? That can only be answered in the market place. We decided to pursue more productive ways to create hydrogen gas on board a vehicle. We still have and manufacture electrolysis hydrogen generators for industrial purposes but they do have poor ROI for most on road use.
Of certain interest, is the efficiency found at singular test points. 10-15% was the average. We found reductions of BSFC in the range of 30-50% at specific load/augmentation points. If you have an application that can take advantage of this, it can certainly be a viable product. The research paper done by Purdue University, mirrors our findings to a large degree, for the diesel engine test.
' Wrote:Quote:All of this is moot of course because there are far better ways of making hydrogen on board.
Such as? Sodium Hydroxide and aluminum reaction? Reforming natural gas?
Electrolysis is the only viable process of producing it while mobile.
POx (partial oxidation) reformers have been in use for decades in various applications. Catalyst aided POx reformers extend the capability to de-polymerize the longer chains found in gasoline and diesel. MIT's plasma reformer increases reformer response to better match varying engine loads and speeds. It has been tested in diesel buses with about a 30% reduction in fuel use. The biggest hurdle other than device longevity, is the ability to match the reformate production with engine needs as there is some lag in gas production. MIT's plasmatron ( the name they have given the device) is capable of reforming the majority of the fuel stream for a fairly large diesel application.
' Wrote:Quote:Once serial hybrids such as the GM Volt become common place
Not going to happen. Low-volume production hybrids like the Prius and Insight are already draining the world's resources to make batteries, plus those batteries have been proven worse for the environment than normal combustion propelled vehicles (materials transport, manufacture, recycling and vehicle safety).
Battery shortage? Really? Ni-Cad and NiMH aside, Lithium-ion batteries are relatively new and still in a development cycle that is relatively steep. Thus, the so called "shortage". Lithium is not rare. It just has been untapped to this point due to the lack of need. Deposits are found on all continents with varying degrees of recover ability. Factories are being built monthly. And the batteries hold such value even after they have reached their "end of life" use as vehicle drive batteries that the overwhelming majority will see the use of their remaining 70% capacity in areas such as load leveling schemes and power storage. Battery recycling will probably approach 100%. There are government grants available to find uses for these power packs.
Unfriendly to the environment? With the BP spill still out of control in the Gulf and a whole region affected for years, I think it is safe to say battery driven vehicles will be no more unfriendly to the environment than traditional fossil fueled vehicles.
' Wrote:Quote:I believe GM will go to direct injected HCCI engines for the Volt in the next model iteration.
If they decide to produce the Volt in the first place.
They will produce the Volt. What with close to a billion dollars invested in R&D and factories for the vehicle and battery packs. There are production test units running around the US and Europe finalizing the software for the broadest consumer appeal as well as working through any traditional problems that shake out. At this point, I wouldn't bet against them to NOT make the Volt.
Homogeneous Charge Compression Ignition (HCCI) engine schemes are already being tested by GM and others. They are speed limited at this point. Hydrogen augmentation is being investigated as a way to extend the operational speed of an HCCI engine. The two constant speed/load points for the Volt's ICE recharger means something like a simple rendition of MIT's plasmatron would be ideal in increasing the ICE fuel economy of the Volt with an HCCI engine.
In summary, there are scientific pathways for HHO to be effective in improving combustion engine efficiency and emissions. The inclusion of sufficient hydrogen in the fuel mix, along with the proper conditions of pressure, temperature and turbulence can extend the lower flammability limit of the hydrocarbon fuel, accelerate the flame front and concentrate the resulting heat release. When timed properly, this concentrated heat release results in an increase in effective cylinder pressure that can give a net gain in energy over the losses needed to produce the hydrogen gas in the first place.
However, larger volumes of hydrogen give even greater benefit, and by using devices such as the compact and powerful MIT "plasmatron", a portion of the fuel stream can easily be reformed on board resulting in significant fuel efficiency gains with a device that will be robust and needs little attention to function in the long term.